COMBUSTION KINETICS

COMBUSTION KINETICS

The chemistry that drives combustion is a very complicated network of reactions. To describe the combustion of a single fuel compound in full chemical detail requires detailed knowledge of hundreds of chemical species that take part in thousands of individual chemical reactions. In turn, each of these reactions has a detailed description in terms of fundamental physical principles.

Thermodynamic laws establish limits to natural and artificial processes, i.e. bounds to the possible paths, but the path actually followed and the pace (the process rate), depends on other circumstances. For instance, Thermodynamics does not say that a piece of paper will burn in air, not even after being ignited, and does not deal with the burning rate; it just says that the system paper/air might reach a more stable equilibrium state (more entropy) by burning, and determines that end state (which might be reached also by secularly-slow oxidation).

It is Kinetics science which deals with how fast things happen: instantly (i.e. more quickly than monitored, as in explosions), evolving at a sizeable pace (i.e. in the monitoring time-span, as in combustion), or at a negligible rate (i.e. more slowly than monitored, as in slow oxidation). For instance, a piece of paper enclosed in a transparent container with more air than the theoretical one, may not burn completely if ignited (e.g. by a concentrated light), because, as oxygen concentration gets reduced, convection and diffusion might not supply enough oxygen to maintain the minimum heat release needed for propagation. Hydrocarbon fuels cannot burn in N2/O2 mixtures if xO2<12% (<5% for H2 fuel), and hydrocarbon fuels cannot burn in CO2/air mixtures if xO2<15% (<6% for H2 fuel). At room temperature, without ignition, the piece of paper in air will oxidize very slowly (unnoticeable to the eye).

FACSIMILE kinetic modelling describes the reaction kinetics, providing tools to better understand and describe combustion processes. For example, models may be explored for insight into the reaction mechanisms of thermal decomposition in the combustion of different materials by using, for instance, Thermogravimetric analysis.

For a direct example of application in combustion kinetics, follow the FACSIMLE application link:


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